You will not be able to remove the .netlify.app domain since this is your sites Netlify sub-domain controlled by Netlify. If you add your own domain, you will be able to remove it.
If you are trying to edit the Netlify sub-domain, you can edit the site’s name in site settings
You currently do not have a domain linked to Netlify. You have what we call a sub-domain and it ends with .netlify.app. This is given to all Netlify sites and you can change the text before .netlify.app by changing your site name in site settings.
If you have a custom domain (which you currently do not have linked to the site) then you will need to add this with the add domain button.